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テート・アミル・カチオンにおける新たな再配置プロセス

Valerije Vrcek1, Martin Saunders, Olga Kronja

  • 1Contribution from the Faculty of Pharmacy and Biochemistry, University of Zagreb, A. Kovacića 1, 10000 Zagreb, Croatia.

Journal of the American Chemical Society
|October 21, 2004
PubMed
まとめ

炭素13のNMRスペクトロスコーピーは,19.5 kcal/molのバリアをテルトアミルカチオンにおける炭素交換に示しています. この再配列には,水素シフトとプロトン化されたサイクロプロパン中間体があり,内外の炭素交換に最も高いエネルギーバリアが認められる.

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