関連する実験動画
Updated: Feb 10, 2026
02:31
Phase Transitions and Effect of Intermolecular Forces
23.3K
鉛のないピエゾセラミクス
Yasuyoshi Saito1, Hisaaki Takao, Toshihiko Tani
1Toyota Central R&D Laboratories, Inc., Nagakute, Aichi, 480-1192, Japan. ysaito@mosk.tytlabs.co.jp
Nature
|November 2, 2004
まとめ
研究者らは新しい無鉛ピエゾ電気セラミックを開発し,鉛ジルコニウムチタナート (PZT) に有望な代替品を提供しました. この新しい材料は,先進的な電子アプリケーションのために,比較可能な電気フィールド誘発の張力と高いピエゾ電気性能を示しています.
科学分野:
- マテリアルサイエンス 材料科学
- 固体物理 固体物理学
- セラミック工学は,セラミック工学です.
背景:
- 鉛ジルコニウムチタナート (PZT) は,電子機器に広く使用されている高性能ピエゾ電気材料です.
- 鉛の毒性に対する懸念は,無鉛の代替品を探す努力を促しています.
- 効果的な無鉛のピエゾ電気セラミックは,まだPZTの代わりになっていません.
研究 の 目的:
- PZTに匹敵する性能を持つ鉛のないピエゾ電気セラミックを開発する.
- ピエゾ電気アプリケーションのためのアルカリニオバートベースのペロブスキート固体溶液を調査する.
- 強化されたピエゾ電気的性質のための高質感のポリクリスタルを達成するために.
主な方法:
- 性ニオバートベースのペロブスキート固体溶液における形態型相境界の発見.
- 高質感のポリクリスタルを作るための加工ルートの開発.
- ピエゾ電気定数d33と電場誘発のストレスを含む,ピエゾ電気特性の特徴.
主要な成果:
- 鉛のないピエゾ電気セラミックが,アクチュエータグレードのPZTに匹敵する電気フィールド誘発の張力を持つことが達成されました.
- このセラミックは,ピエゾ電気定数d33が300 pC N(-1) を超えるピエゾ電気定数d33を示しています.
- 材料のテクスチャリングにより,ピークd33の416 pCN (−1) と,温度に関係ないストレスを得られた.
結論:
- 性ニオバ酸塩を基にした新しい無鉛ピエゾ電気セラミックが成功裏に開発されました.
- この材料は,センサーとアクチュエータの鉛ベースのPZTに適した,高性能な代替材料を提供します.
- 達成されたテクスチャリングとフェーズ境界のエンジニアリングは,その優れたピエゾ電気的性質の鍵です.
関連する概念動画
Phase Transitions
23.3K
Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
23.3K
Properties of Transition Metals
30.0K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
30.0K
Cooperative Allosteric Transitions
8.8K
Cooperative allosteric transitions can occur in multimeric proteins, where each subunit of the protein has its own ligand-binding site. When a ligand binds to any of these subunits, it triggers a conformational change that affects the binding sites in the other subunits; this can change the affinity of the other sites for their respective ligands. The ability of the protein to change the shape of its binding site is attributed to the presence of a mix of flexible and stable segments in the...
8.8K
Phase Transitions: Vaporization and Condensation
21.5K
The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules...
21.5K
Phase Transitions: Sublimation and Deposition
20.3K
Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
20.3K
Phase Transitions: Melting and Freezing
15.2K
Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
15.2K