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Updated: Jul 20, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

エチレンテトレメリゼーション:例外的に高い選択性で1オクテンを生成するための新しい経路

Annette Bollmann1, Kevin Blann, John T Dixon

  • 1R & D Division, Sasol Technology (Pty) Ltd., 1 Klasie Havenga Road, Sasolburg 1947, South Africa.

Journal of the American Chemical Society
|November 13, 2004
PubMed
まとめ

研究者らは,選択的1オクトン生成のための新しいエチレン四重化法を開発しました. このブレークスルーは,線形低密度ポリエチレン (LLDPE) の重要なコモノマーへのより効率的な経路を提供します.

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Preparation of Alkynes: Alkylation Reaction02:27

Preparation of Alkynes: Alkylation Reaction

Introduction
Alkylation of terminal alkynes with primary alkyl halides in the presence of a strong base like sodium amide is one of the common methods for the synthesis of longer carbon-chain alkynes. For example, treatment of 1-propyne with sodium amide followed by reaction with ethyl bromide yields 2-pentyne.
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Preparation of Alkynes: Dehydrohalogenation

Introduction
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The Diels–Alder reaction is one of the robust methods for synthesizing unsaturated six-membered rings. The reaction involves a concerted cyclic movement of six π electrons: four π electrons from the diene and two π electrons from the dienophile.
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Polymer Classification: Stereospecificity

Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
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