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The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
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螺旋型のエチニルヘリセンのオリゴマーの展開速度に対する芳香剤の顕著な効果

Hiroki Sugiura1, Yasuko Nigorikawa, Yuto Saiki

  • 1Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Aoba, Sendai 980-8578, Japan.

Journal of the American Chemical Society
|November 13, 2004
PubMed
まとめ

光学的に活性なエチニルヘリセンのオリゴマーは,溶液に展開する螺旋状の構造を形成します. 展開速度は,溶媒の芳香性特性に大きく依存し,溶媒の柔らかさと相関しています.

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