Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

Ionic Bonds00:42

Ionic Bonds

When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.Opposing Charges Hold Ions Together in Ionic CompoundsIonic bonds are reversible electrostatic interactions between ions with...
Intermolecular Forces03:13

Intermolecular Forces

Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Intermolecular Forces03:13

Intermolecular Forces

Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Electrochemical Systems01:24

Electrochemical Systems

Electrochemical systems provide a fascinating insight into the dynamic interplay of charged species within various phases. One notable example is the interaction between a membrane permeable to K⁺ ions but not to Cl⁻ ions, separating an aqueous KCl solution from pure water. As K⁺ ions diffuse through the membrane, they generate net charges on each phase, leading to a potential difference between them.Similarly, when a piece of Zn is immersed in an aqueous ZnSO₄ solution, the Zn metal, composed...
The Electrical Double Layer01:30

The Electrical Double Layer

In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

Photophysical behavior of mono- and bis(2'-hydroxyphenyl)-6-(4'-diphenylaminophenyl)pyrimidines: Interplay of ESIPT, ICT, and vibrational nonradiative decay.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy·2026
Same author

Thiourea-based multifunctional fluorescent materials: From metal and anion detection to antibacterial polymer films.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy·2026
Same author

Antenna effect of luminescent levofloxacin-lanthanide complexes in biological medium.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy·2026
Same author

Physician treatment decisions for hormone receptor-positive, HER2-negative early breast cancer in young patients: a Latin American survey.

Therapeutic advances in medical oncology·2025
Same author

Unveiling Adenine H‑bonded Hexads: Hierarchical Self-Assembly for Helical Columnar Functional Materials.

JACS Au·2025
Same author

Pyrimidine-Based Four-Coordinate O^N^O Boron Complexes: Synthesis, Photophysical and Theoretical Studies, and TADF-Based OLED Devices.

Chemistry (Weinheim an der Bergstrasse, Germany)·2025

関連する実験動画

Updated: Jul 16, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

固体フランにおける分子間電荷移転と水素結合.

Manuel Montejo1, Amparo Navarro, Gordon J Kearley

  • 1Department of Physical and Analytical Chemistry, University of Jaén, 23071 Jaén, Spain.

Journal of the American Chemical Society
|November 19, 2004
PubMed
まとめ

密度関数理論と非弾性中性子散乱は,C-H...piとC-H...O結合を含む固体フランの分子間相互作用を明らかにする. 電子の移転は隣接するフラン環の間に発生し,ポリフラン鎖の相互作用をモデル化します.

科学分野:

  • 固体化学 固体化学
  • 計算化学はコンピュータ化学である.
  • マテリアルサイエンス 材料科学

背景:

  • 分子間相互作用を理解することは,材料の性質を予測するために極めて重要です.
  • フランの結晶構造と電子特性は,結合ポリマーにとって興味深いものです.

研究 の 目的:

  • 計算的および実験的方法を使用して,固体フランの分子間相互作用を調査する.
  • フーラン二重体における電子移転とポリフーランとの関連性をモデル化するため.

主な方法:

  • 構造的および電子的分析のための密度関数理論 (DFT) 計算.
  • 振動動力学の不弾性中性子散射 (INS) 測定について.
  • 相互作用分析のための分子内の原子 (AIM) と自然結合軌道 (NBO) の理論.

主要な成果:

  • 固体フランにおけるC-H...pi,C-H...O,H...Hの相互作用を特定した.
  • H結合ジメルの隣接するフラン環間の電子電荷の移転を観測した.
  • 計算された振動モードと実験的な振動モードが相関しており,水素が関与する振動モードの不一致がある.

結論:

さらに関連する動画

Finite Element Modelling of a Cellular Electric Microenvironment
08:23

Finite Element Modelling of a Cellular Electric Microenvironment

Published on: May 18, 2021

Using Laser Scanning Microscopy to Determine Electromigration in Molybdenum Disilicide
09:41

Using Laser Scanning Microscopy to Determine Electromigration in Molybdenum Disilicide

Published on: May 23, 2025

関連する実験動画

Last Updated: Jul 16, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

Finite Element Modelling of a Cellular Electric Microenvironment
08:23

Finite Element Modelling of a Cellular Electric Microenvironment

Published on: May 18, 2021

Using Laser Scanning Microscopy to Determine Electromigration in Molybdenum Disilicide
09:41

Using Laser Scanning Microscopy to Determine Electromigration in Molybdenum Disilicide

Published on: May 23, 2025

  • 固体フランにおける分子間力の性質と重要性を確立した.
  • ポリフランにおけるエンドグループ相互作用のモデルを,フラン二元体の発見に基づいて提案した.
  • Pi-システム相互作用に依存する他の結合ポリマーへの適用性を強調した.