ズウィッテリオンのPd (II) センターで媒介されるアミンの活性化プロセスの合成,構造,および機械的側面

Connie C Lu1, Jonas C Peters

  • 1Division of Chemistry and Chemical Engineering, Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA.

まとめ

ズウィテリオンパラジウム複合体は,トライキラミン内のC-H結合を選択的に活性化し,イミニウム添加物を形成します. ベータ水素除去は速度を制限するステップであり,溶媒の極性および複合電荷の影響を受けます.

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