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Updated: Jul 14, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
10:12

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

Published on: April 4, 2014

交互結合サイクロヘクサディエノンのダイエルス・アルダーサイクル添加過程におけるオクサスピロ環によるステレオ選択性制御:同酸素現象

Katsuo Ohkata1, Yukiko Tamura, Brandon B Shetuni

  • 1Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan.

Journal of the American Chemical Society
|December 23, 2004
PubMed
まとめ

この研究では,スパイロサイクルのサイクロヘキサディエノンのダイエルス・アルダー反応を調査し,ステレオ化学的結果がダイノフィール構造と電子効果に依存することを発見しました. 溶媒の極性によって,製品の分布はほとんど影響を受けなかった.

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