触媒プロペンのポリメリゼーションにおける二次金属アルキルの反応性: "休眠連鎖"はどの程度休眠しているのでしょうか?

Vincenzo Busico1, Roberta Cipullo, Valeria Romanelli

  • 1Dipartimento di Chimica, Università di Napoli Federico II, Via Cintia, 80126 Naples, Italy. busico@unina.it

PubMed
まとめ

この研究では,新しい触媒を用いたジルコニウムポリメリルの休眠連鎖濃度と反応性を直接測定した. 結果は,二次ポリメリルはプロペンと悪い反応をし,潜在的に不活性な鎖を蓄積することを示しています.

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