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Updated: Jul 17, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

カチオンパラジウムアルキル複合体のアクリロニトリル挿入反応

Fan Wu1, Stephen R Foley, Christopher T Burns

  • 1Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, IL 60637, USA.

Journal of the American Chemical Society
|February 11, 2005
PubMed
まとめ

アクリロニトリル (AN) を含むパラジウム触媒は,ANを挿入するN結合アダクトを形成し,集合種となる. 集積と低挿入反応性は,これらの触媒でANのポリメリゼーションを妨げます.

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