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Updated: Jul 19, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

中性およびアニオン性Pd (II) 複合体のパラジウムメチル結合にアクリロニトリルを挿入する

Laurent F Groux1, Thomas Weiss, Dastigiri N Reddy

  • 1Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, Canada T2N 1N4.

Journal of the American Chemical Society
|February 11, 2005
PubMed
まとめ

この研究では,パラジウム (II) メチル化合物が,Pd-Me結合に2,1挿入を介してアクリロニトリル (AN) と反応し,ダイマーとトリマーを形成する方法を詳細に説明しています. 負の電荷のリガンドは,この重要な調整ポリメリゼーション反応を加速します.

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