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Updated: Jul 20, 2026

Reliable Mechanochemistry: Protocols for Reproducible Outcomes of Neat and Liquid Assisted Ball-mill Grinding Experiments
13:05

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Published on: January 23, 2018

塩基触媒による水素化:触媒と基板構造と溶解の効果を合理化する

Bun Chan1, Leo Radom

  • 1Contribution from the School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia. chan_b@chem.usyd.edu.au

Journal of the American Chemical Society
|February 24, 2005
PubMed
まとめ

カーボニル化合物の塩基触媒化水素化は,S(N) 2反応のように振る舞い,ガス相反応は低バリア,溶液相反応は高バリアを示す. 移行構造の組み立ては,反応速度を制限する.

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