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Updated: Jul 17, 2026

Enzymatic Cascade Reactions for the Synthesis of Chiral Amino Alcohols from L-lysine
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Enzymatic Cascade Reactions for the Synthesis of Chiral Amino Alcohols from L-lysine

Published on: February 16, 2018

3-ヒドロキシ-2,2-ジフローロ酸を生成する新しい選択的ハロフォーム型反応:そのメカニズムの理論的研究

Santiago Olivella1, Albert Solé, Oscar Jiménez

  • 1Departament de Química Orgànica Biologica, Institut d'Investigacions Químiques i Ambientals de Barcelona, CSIC, Jordi Girona 18, 08034-Barcelona, Catalonia, Spain. sonqtc@cid.csic.es

Journal of the American Chemical Society
|February 24, 2005
PubMed
まとめ

この研究は,特定のケトンがCO-CF(3) 結合を裂く新しいハロフォーム型反応を説明しています. 密度関数理論の計算は,フッ素の安定化により,CO-CF ((3) 結合経路が好まれていることを明らかにします.

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