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Updated: Jul 12, 2026

A Method to Manipulate Surface Tension of a Liquid Metal via Surface Oxidation and Reduction
09:20

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Published on: January 26, 2016

ディメタロセンの二分法:サンドイッチ化合物における同軸対垂直の二重金属単位

Yaoming Xie1, Henry F Schaefer Iii, R Bruce King

  • 1Department of Chemistry and Center for Computational Chemistry, University of Georgia, Athens, Georgia 30602, USA.

Journal of the American Chemical Society
|March 3, 2005
PubMed
まとめ

理論的研究により,ジンコセーン,ニケロセーン,カップリセンのようなダイメタロセンは,金属と金属の結合と構造的な好みを有していることが明らかになった. DFT計算では,ニケロセンとカップリセンのシングレット状態が,垂直の金属対金属結合を持つ低エネルギー構造を好むことが示されています.

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