関連する実験動画

Updated: Jul 11, 2026

Spin Saturation Transfer Difference NMR (SSTD NMR): A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes
11:44

Spin Saturation Transfer Difference NMR (SSTD NMR): A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes

Published on: November 12, 2016

ディエノフィルの歪みと置換剤効果は,分子内ディエルス-アルダーサイクル添加の反応速度に影響する: DFTの研究

Kelli S Khuong1, Chris M Beaudry, Dirk Trauner

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, USA.

Journal of the American Chemical Society
|March 18, 2005
PubMed
まとめ

計算による研究により,5-ビニル-1,3-サイクロヘキサディエンの置換物位が,分子内サイクロアディション反応にどのように影響するかが明らかになった. 反応物質と移行状態におけるステリック効果は,同位体間の観測された実験的速度の違いを説明する.

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