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Updated: Jul 12, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

ハロオレフィンとアニリデスの触媒結合

Vladimir G Zaitsev1, Olafs Daugulis

  • 1Department of Chemistry, University of Houston, Houston, Texas 77204-5003, USA.

Journal of the American Chemical Society
|March 24, 2005
PubMed
まとめ

この研究では,パラジウム (II) とβ-ヘテロ原子の除去を用いたアリレーションのための新しい触媒的方法が導入されています. このアプローチは,アルケン-アレン結合反応に対する機能群の許容性を改善します.

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Catalysis02:50

Catalysis

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Acid Halides to Carboxylic Acids: Hydrolysis

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Acid Halides to Esters: Alcoholysis01:12

Acid Halides to Esters: Alcoholysis

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Esters to Carboxylic Acids: Acid-Catalyzed Hydrolysis

Hydrolysis of esters under acidic conditions proceeds through a nucleophilic acyl substitution. In the presence of excess water, the reaction proceeds in a reversible manner, forming carboxylic acids and alcohols.
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Catalysis

Catalysis influences the rate of chemical reactions by providing an alternative reaction pathway with lower activation energy. A catalyst speeds up a reaction, but it is not consumed during the process. The fundamental principle of catalysis is the ability of a catalyst to alter the reaction mechanism, often introducing a more efficient pathway than the uncatalyzed process.In a catalyzed reaction, the catalyst participates directly in the reaction mechanism. It interacts with reactants to form...