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Updated: Aug 18, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

水素シランの分子間および分子内,プラチナ触媒,無受容体脱水誘導結合は,アリルおよびアリファティックメチルC-H結合と結合する

Naofumi Tsukada1, John F Hartwig

  • 1Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut 06520-8107, USA.

Journal of the American Chemical Society
|April 7, 2005
PubMed
まとめ

プラチナ触媒は,アレンとアルケンのC-H結合を持つシルアンの効率的な分子間および分子内脱水酸化結合を可能にします. これらの反応は,固体的にアクセス可能な場所と,電子が少ない場所の選択性を示し,潜在的な不可逆性を示唆しています.

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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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