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Updated: Aug 14, 2026

Electroactive Polymer Nanoparticles Exhibiting Photothermal Properties
10:16

Electroactive Polymer Nanoparticles Exhibiting Photothermal Properties

Published on: January 8, 2016

デンドリマーで封じ込められたPdナノ粒子は,静止反応のための水性,室温の触媒として使用されます

Joaquin C Garcia-Martinez1, Raphael Lezutekong, Richard M Crooks

  • 1Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842-3012, USA.

Journal of the American Chemical Society
|April 7, 2005
PubMed
まとめ

デンドリマーで封じ込められたパラジウムナノ粒子は,穏やかな水性条件下で効率的にスティル結合反応を触媒化する. このブレークスルーは,最小限のパラジウム触媒を使用し,複雑な有機分子を合成するためのよりグリーンなアプローチを提供します.

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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...