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Updated: Jun 25, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
12:30

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Published on: April 9, 2018

鉄複合体 bis ((ベンゼン-1,2-ディチオラト) の S,S'-協調リガンドのレドックス無無害性

Kallol Ray1, Eckhard Bill, Thomas Weyhermüller

  • 1Max-Planck-Institute for Bioinorganic Chemistry, Stiftstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany.

Journal of the American Chemical Society
|April 14, 2005
PubMed
まとめ

この研究は,ディチオラートリガンドを持つ鉄複合体は高価鉄を形成しないことを明らかにしています. 代わりに,リガンドの急性モノアニオンが存在し,鉄 (III) 複合体における反鉄磁性スピン結合につながります.

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