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Updated: Jul 5, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
06:31

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Published on: November 27, 2015

ベータアミノカルボキシアミドをリチウムヘキサメチルジジラジライドで可逆エノリゼーションする

Anne J McNeil1, David B Collum

  • 1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.

Journal of the American Chemical Society
|April 14, 2005
PubMed
まとめ

ベータアミノカルボキシアミドは,リチウムヘクサメチルジジラジル化 (LiHMDS) とダイアステロ選択性アルキル化によるエノリゼーションを受けます. ベータアミノ群はエノ化を促進し,これは可逆であり,複雑なリチウム集積を形成する.

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