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Updated: Jul 31, 2026

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes
09:08

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes

Published on: February 27, 2017

プロピレンとのコポリメリゼーションにおけるブタジエンの水素化された1,4-挿入は,同異種ジルコノセンの触媒を用いて行われる

Takeshi Ishihara1, Takeshi Shiono

  • 1Japan Chemical Innovation Institute, AIST Tsukuba, Central 5-8, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.

Journal of the American Chemical Society
|April 21, 2005
PubMed
まとめ

特定のジルコノセンの触媒を用いたプロピレンとブタジエンの共ポリマー化中の水素化は,選択的に1,2-挿入されたブタジエンの単位を生成し,触媒の活性を大幅に高め,分岐を防止します.

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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the surface of...
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