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Updated: Jul 20, 2026

Design and Synthesis of a Reconfigurable DNA Accordion Rack
07:44

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Published on: August 15, 2018

エーテルにおける単一結合C−C結合定数は,主にN−シグマ移位によって決定されるものではない

Charles L Perrin1, Máté Erdélyi

  • 1Department of Chemistry, University of California, San Diego, La Jolla, California 92093-0358, USA. cperrin@ucsd.edu

Journal of the American Chemical Society
|April 28, 2005
PubMed
まとめ

この研究では,炭素-炭素結合定数 (1JCC) をエーテルで測定し,二面角への依存が典型的な移位モデルとは異なることを発見しました. 結果は,デロカライゼーションではなく,二極相互作用が,主にこれらの結合定数に影響することを示唆しています.

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