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Updated: Jul 10, 2026

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アセチレンE2H2 (E=Si-Pb) の重原子類型は,なぜ異常な構造を示しているのでしょうか?

Matthias Lein1, Andreas Krapp, Gernot Frenking

  • 1Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany.

Journal of the American Chemical Society
|April 28, 2005
PubMed
まとめ

14組のより重い水素であるE(2) H(2) (E = Si-Pb) は,炭素と比べて電子相互作用の違いにより,異常な非平面幾何学を採用しています. これらの構造は,特定の軌道貢献と静電相互作用によって安定化されます.

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