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Updated: Jul 10, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

移行金属で触媒化されたアルレンとビニルcyclopropanesの分子間 [5+2] と [5+2+1] サイクル添加物である

Hermann A Wegner1, Armin de Meijere, Paul A Wender

  • 1Departments of Chemistry and Molecular Pharmacology, Stanford University, Stanford, CA 94305, USA.

Journal of the American Chemical Society
|May 5, 2005
PubMed
まとめ

研究者らは,二機能アレンとビニルcyclopropanesを使用して新しいRh (I) -触媒化された [5+2]サイクル添加反応を報告しています. この方法は,サイクルロードダクトを効率的に合成し,炭素一酸化物で,3つの構成要素 [5+2+1] のサイクロアディションによって8つの構成のリングを形成します.

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