イミノキシル/オキシム自己交換反応の理論的研究. 5中心の,周期的な陽子カップル電子移転です

Gino A DiLabio1, K U Ingold

  • 1National Institute for Nanotechnology, National Research Council, 9107 116th Street, Edmonton, Alberta, Canada T6G 2V4. Gino.DiLabio@nrc.ca

まとめ

酸素中心のラジカルは,急速な陽子結合電子移転 (PCET) を受けます. イミノキシルラジカル自己交換反応は,酸素中心のラジカルと対照的に,周期的なPCETメカニズムを経由して発生する.

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