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Updated: Jul 19, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
08:15

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups

Published on: February 11, 2012

グループ13のより重い元素の安定した単核根幹アニオン: [(tBu2MeSi) 3E.-]. [K+(2.2.2-Cryptand) ] (E = Al, Ga) となっている

Masaaki Nakamoto1, Tomoki Yamasaki, Akira Sekiguchi

  • 1Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.

Journal of the American Chemical Society
|May 12, 2005
PubMed
まとめ

研究者らは,より重いグループ13の元素,トリス・ディ・テート・ブチル・メチル・シリル・アルミニウム・ガリウムから,初めて単離可能な単核基アニオンを合成した. これらの安定した,深い赤色の結晶は,その根中心の周りにほぼ平面的な幾何学を示しています.

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