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Updated: Jul 25, 2026

Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods
05:41

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光誘導水素生成のためのヘテロレプティックイリジウム複合体の発見と高通量スクリーニング

Jonas I Goldsmith1, William R Hudson, Michael S Lowry

  • 1Department of Chemistry, Princeton University, New Jersey 08544, USA.

Journal of the American Chemical Society
|May 19, 2005
PubMed
まとめ

研究者らは,水から効率的な光誘導水素生成のための新しいイリジウム複合体を開発した. これらの触媒は,既存の光敏感剤と比較して,水素生成効率が著しく高いことを実証しました.

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Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the surface of...
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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Photochemical Electrocyclic Reactions: Stereochemistry

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Heterogeneous Catalysis

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