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Updated: Jul 9, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

[{シロックス}2Mo=NtBu]2{mu-Hg}の3センター4電子結合は反応性を制御し,フロンティア軌道ではジモリブデンパイ結合エネルギー推定が可能である

Devon C Rosenfeld1, Peter T Wolczanski, Khaldoon A Barakat

  • 1Department of Chemistry & Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853, USA.

Journal of the American Chemical Society
|June 9, 2005
PubMed
まとめ

この研究は,新種の水銀橋型ジモリブデン複合体の合成と性質を詳細に説明しています. この水銀の橋渡し複合体は,ユニークな電子構造と核愛素に対する反応性を示し,モリブデン-リガンド結合に影響を与えます.

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