関連する実験動画

Updated: Jul 9, 2026

Probing C84-embedded Si Substrate Using Scanning Probe Microscopy and Molecular Dynamics
13:58

Probing C84-embedded Si Substrate Using Scanning Probe Microscopy and Molecular Dynamics

Published on: September 28, 2016

吸附された1,3-サイクロヘキサジエンのサイクロアディションイソメリゼーションは,Si(100) - 2x1の表面に:最初の隣人相互作用

Hee Soon Lee1, Cheol Ho Choi, Mark S Gordon

  • 1Department of Chemistry, College of Natural Sciences, Kyungpook National University, Taegu 702-701, South Korea.

Journal of the American Chemical Society
|June 9, 2005
PubMed
まとめ

本研究では,Si{100}表面での1,3-サイクロヘキサジンの反応を調査し,新しい製品と反応経路を特定しました. 運動および熱力学的制御を理解することは,実験的な表面科学の結果を解釈する鍵です.

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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

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Electrophilic 1,2- and 1,4-Addition of HX to 1,3-Butadiene

The electrophilic addition of hydrogen halides such as HBr to alkenes and nonconjugated dienes gives a single product as per Markovnikov’s rule.
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Cycloaddition Reactions: Overview

Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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[4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction

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[3,3] Sigmatropic Rearrangement of Allyl Vinyl Ethers: Claisen Rearrangement

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