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Updated: Jul 6, 2026

Temperature-programmed Deoxygenation of Acetic Acid on Molybdenum Carbide Catalysts
08:15

Temperature-programmed Deoxygenation of Acetic Acid on Molybdenum Carbide Catalysts

Published on: February 7, 2017

パラジアム触媒によるアルコールの有酸素酸化におけるリガンド効果を説明するために,機械的および計算的研究を用いた

Mitchell J Schultz1, Ryan S Adler, Wiktor Zierkiewicz

  • 1Contribution from the Department of Chemistry, University of Utah, Salt Lake City, UT 84112, USA.

Journal of the American Chemical Society
|June 9, 2005
PubMed
まとめ

この研究では,パラジウムアセテートとトリエチラミンは,典型的なβ-ヒドリド除去機構とは異なる速度制限デプロトネーションを通じてアルコール酸化を触媒化することが明らかになりました. このユニークな経路は,室温の触媒を可能にします.

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