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Updated: Jul 13, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
08:12

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Published on: August 16, 2018

イットrium-biphenyldiol複合体を用いたアルファ,ベータ不飽和エステルの触媒的非対称エポキシデーション

Hiroyuki Kakei1, Riichiro Tsuji, Takashi Ohshima

  • 1Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|June 23, 2005
PubMed
まとめ

この研究は,イットリウム-キラルバイフェニルダイオール触媒を用いた不飽和エステルの新種の触媒非対称エポキシデーションを提示しています. この方法は,高収量およびエナチオセレクティブ性を持つ有価なアルファ,β-エポキシエステルを効率的に生成します.

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