ニトロベンゼンの選択的オーソヒドロキシル化と,H5PV2Mo10O40ポリオキシメタレートによって触媒化された分子酸素によるオートヒドロキシル化

Alexander M Khenkin1, Lev Weiner, Ronny Neumann

  • 1Department of Organic Chemistry and Chemical Research Support Unit, Weizmann Institute of Science, Rehovot, Israel 76100.

まとめ

この研究では,ポリオキソメタラート触媒と酸素を使用して,ニトロベンゼンから2ニトロフェノールへの地域選択的酸化が実証されています. 証拠は,オートホー位置での分子内相互作用経由で急性中間形態を示唆しています.

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