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Updated: Jul 5, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
14:07

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus

Published on: October 3, 2014

メチルグループは,ボロンクラスターで電子を贈るのか,それとも取り除くのか? o-カルボランのパーメチル化

Francesc Teixidor1, Gemma Barberà, Albert Vaca

  • 1Institut de Ciència de Materials de Barcelona (CSIC), Campus U.A.B., E-08193 Bellaterra, Spain.

Journal of the American Chemical Society
|July 21, 2005
PubMed
まとめ

ボロンクラスターのメチルグループは,一般的な仮定に反して,電子を取り除くグループとして作用します. この電子効果は反応性に影響を及ぼし,これは,ペルメチル化ボロンクラスターに対する核愛性の攻撃によって示されている.

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