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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

アロマティックC-H結合のステリックに誘導された機能化:アレンとヘテロサイクルのオートーからサイアノ群への選択的ボルイレーション

Ghayoor A Chotana1, Michael A Rak, Milton R Smith

  • 1Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, USA.

Journal of the American Chemical Society
|July 28, 2005
PubMed
まとめ

この研究では,2位位置のベンゾニトリルを機能化するために,イリジウム触媒によるボリレーションを導入し,C-H活性化のための新しい経路を提供しています. この方法は,ヘテロサイクルにも適用され,特定のケースでは選択的ディボリレーションを可能にします.

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