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Updated: Aug 16, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
07:14

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

Published on: May 12, 2023

単核M(II) コンプレックス (M = Pt, Pd, Cu) を有機柱状の協調ケージ内に分別的に積み重ねることで,金属と金属の d-d 相互作用が起こります

Michito Yoshizawa1, Kosuke Ono, Kazuhisa Kumazawa

  • 1Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

Journal of the American Chemical Society
|August 4, 2005
PubMed
まとめ

2つの金属複合体,プラチナ (Pt) とパラジウム (Pd) は,調整ケージに積み重ねられ,金属と金属の相互作用によるユニークなスペクトル信号を示しました. 銅 (Cu) 複合体は,類似の相互作用による電子スピン-スピン結合を示した.

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