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Updated: Jul 18, 2026

Sequencing of Plant Wall Heteroxylans Using Enzymic, Chemical (Methylation) and Physical (Mass Spectrometry, Nuclear Magnetic Resonance) Techniques
11:49

Sequencing of Plant Wall Heteroxylans Using Enzymic, Chemical (Methylation) and Physical (Mass Spectrometry, Nuclear Magnetic Resonance) Techniques

Published on: March 24, 2016

アルファアリル置換ビニルカチオンにおけるシグマデロカライゼーション対パイ共振

Thomas Müller1, Dominik Margraf, Yvonne Syha

  • 1Institut für Anorganische und Analytische Chemie der Johann Wolfgang Goethe Universität Frankfurt, Marie Curie-Strasse 11, D 60439 Frankfurt/Main, Federal Republic of Germany. dr.thomas.mueller@chemie.uni-frankfurt.de

Journal of the American Chemical Society
|August 4, 2005
PubMed
まとめ

研究者らは,アリル基とシリル基で新しいビニルカチオンを合成し,安定させた. これらの化合物は,NMRとコンピューティング研究によって確認された,パイ共振とシグマ移転を通じて有意な安定化を示します.

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