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Updated: Jul 10, 2026

Spin Saturation Transfer Difference NMR (SSTD NMR): A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes
11:44

Spin Saturation Transfer Difference NMR (SSTD NMR): A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes

Published on: November 12, 2016

水素交換反応における幾何学的相効果の理論的研究

Juan Carlos Juanes-Marcos1, Stuart C Althorpe, Eckart Wrede

  • 1School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.

Science (New York, N.Y.)
|August 20, 2005
PubMed
まとめ

分子反応における幾何学的相効果は,しばしばマスクされています. 水素交換反応の新たな分析により,異なる反応経路タイプがこれらの効果を無効化し,量子力学への洞察を提供することを明らかにした.

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To understand this phenomenon, consider the elementary reaction:
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