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Updated: Jul 15, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
06:31

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Published on: November 27, 2015

ニトロンとアクロレインの非対称1,3-二極サイクロアディション反応は,キラルルイス酸としてビスチタニウム触媒を用いて行われる

Taichi Kano1, Takuya Hashimoto, Keiji Maruoka

  • 1Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.

Journal of the American Chemical Society
|August 25, 2005
PubMed
まとめ

キラル型ビスチタニウム ((IV) オキシド触媒は,非対称の1,3-二極サイクロアディション反応を効率的に促進する. この方法は,高いエナチオセレクティブ性を持つイソクサゾリジンを生成し,ステレオセレクティブ合成におけるその有用性を実証しています.

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