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Updated: Jul 14, 2026

Qualitative Identification of Carboxylic Acids, Boronic Acids, and Amines Using Cruciform Fluorophores
09:46

Qualitative Identification of Carboxylic Acids, Boronic Acids, and Amines Using Cruciform Fluorophores

Published on: August 19, 2013

C-H...O水素結合によるフォスフィン基板認識:非対称なパウソン・カンド反応への応用

Jordi Solà1, Antoni Riera, Xavier Verdaguer

  • 1Unitat de Recerca en Síntesi Asimètrica (URSA-PCB), Parc Científic de Barcelona and Departament de Química Orgànica, Universitat de Barcelona, c/Josep Samitier, 1-5, E-08028 Barcelona, Spain.

Journal of the American Chemical Society
|September 30, 2005
PubMed
まとめ

PuPHOSとCAMPHOSのリガンドに含まれる独特のメチンの分子は,水素結合ドナーとして作用する. この相互作用は,ダイアステロセレクティブリガンド交換を駆動し,高エナチオセレクティブ性を持つ非対称なパウソン・カンド反応を可能にします.

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Crossed Aldol Reaction Using Weak Bases

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