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Updated: Jul 16, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
14:07

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus

Published on: October 3, 2014

[CpOsH4(L) ]+ (L = PPh3,AsPh3,およびPCy3) の分子二水素活性化に対する電子およびステリック効果

Charles Edwin Webster1, Christopher L Gross, Dianna M Young

  • 1Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA.

Journal of the American Chemical Society
|October 27, 2005
PubMed
まとめ

オスミウム二水素複合体は独特の"延長された"H2リガンドを示しており,その指向と結合長さはステリックおよび電子的要因の影響を受けます. これらの発見は,有機金属化学における二水素リガンドの行動に関する重要な洞察を明らかにします.

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