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Updated: Jul 6, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

容易なRu-H2の異解活性化と,リガンド内の基本的なN-センターによって支援される分子内プロトン伝達

Félix A Jalón1, Blanca R Manzano, Agustín Caballero

  • 1Departamento de Química Inorgánica, Orgánica y Bioquímica, IRICA, Departamento de Química Física, Universidad de Castilla-La Mancha, Avda. C. J. Cela 10, 13071 Ciudad Real, Spain. Felix.Jalon@uclm.es

Journal of the American Chemical Society
|November 3, 2005
PubMed
まとめ

[Cp*RuH(P) ]複合体のフォスフィンPPh2pyリガンドは,反転可能な陽子の移転とH2の放出を促進します. この振る舞いは,触媒によるデウテリウムラベリングを可能にし,容易な異解性H2活性化を示している.

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