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Updated: Jul 9, 2026

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis
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Zn(CN) 2における負の熱膨張のための横断振動機構の直接観察:原子対分布関数解析

Karena W Chapman1, Peter J Chupas, Cameron J Kepert

  • 1School of Chemistry, University of Sydney, Sydney, NSW 2006 Australia.

Journal of the American Chemical Society
|November 3, 2005
PubMed
まとめ

Zn(CN) 2における負の熱膨張 (NTE) は,シアン化物ブリッジの横断的移動の増加によって引き起こされます. この構造的洞察は,個々の債券の拡大にもかかわらず,NTEを説明しています.

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