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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Published on: July 28, 2018

チタンのアルキリディネによって促進される分子間C-H結合の活性化

Brad C Bailey1, Hongjun Fan, Erich W Baum

  • 1Department of Chemistry, Molecular Structure Center and School of Informatics, Indiana University, Bloomington, Indiana 47405, USA.

Journal of the American Chemical Society
|November 17, 2005
PubMed
まとめ

この研究は,一時的なチタンのアルキリジンの複合体が,アルキリジンの経路経由で容易にC-H結合を追加することを明らかにしています. アルファ-水素抽出は,このチタン化学における速度を決定するステップとして識別されます.

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