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Updated: May 1, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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高度にエナチオセレクティブの銅 (((I) -フェスルフォスがアゾメチンイリドの1,3-二極サイクロアディションを触媒化した

Silvia Cabrera1, Ramón Gómez Arrayás, Juan C Carretero

  • 1Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid, Spain.

Journal of the American Chemical Society
|November 25, 2005
PubMed
まとめ

新しいキラルルイス酸触媒は,非対称な1,3-二極サイクロアディション反応を効率的に駆動します. このシステムは,ケチミン由来基板であっても,アゾメチンイリドの高収量と例外的なエナチオ選択性を達成します.

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