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Updated: Jun 30, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 21, 2014

2-ピリジル有機金属のクロスカップリング問題への解決策:ピリジンN酸化物の地域選択的触媒的直接アリレーション

Louis-Charles Campeau1, Sophie Rousseaux, Keith Fagnou

  • 1Center for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada K1N 6N5.

Journal of the American Chemical Society
|December 22, 2005
PubMed
まとめ

ピリジンN酸化物は,2位でアリルブロミドと直接アリル化され,パラジウム触媒のクロスカップリング反応において,2-メタラピリジンに安定的かつ費用対効果の高い代替品となる.

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