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Updated: Jul 19, 2026

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction
12:22

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction

Published on: February 4, 2013

SmI2への水添加のメカニズム的影響:土壌への影響と移行状態への影響

Edamana Prasad1, Robert A Flowers

  • 1Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, USA.

Journal of the American Chemical Society
|December 22, 2005
PubMed
まとめ

サマリウムダイオイド (SmI2) に水を加えると,その溶解と集積状態を変えることで,より強力な還元剤が作られます. これはベンジルブロミド還元のための反応機構に影響を与え,SmI2-水システムの複雑さを強調します.

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