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Updated: Jun 25, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
10:12

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

Published on: April 4, 2014

トリス ((トリメチルシリル) シリル支配アルデヒドクロスアルドールカスケード反応

Matthew B Boxer1, Hisashi Yamamoto

  • 1Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, IL 60637, USA.

Journal of the American Chemical Society
|January 5, 2006
PubMed
まとめ

Tris ((trimethylsilyl) silyl (TTMSS) グループは,アルデヒドクロスアルドール反応を効率的に可能にし,高い選択性を持つ複雑なヒドロキシアルデヒドを生成します. この触媒的方法は,有機合成において前例のない反応性とステレオ化学的制御を提供します.

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