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Updated: Jul 9, 2026

Reliable Mechanochemistry: Protocols for Reproducible Outcomes of Neat and Liquid Assisted Ball-mill Grinding Experiments
13:05

Reliable Mechanochemistry: Protocols for Reproducible Outcomes of Neat and Liquid Assisted Ball-mill Grinding Experiments

Published on: January 23, 2018

低座標鉄二酸化窒素複合体の研究

Jeremy M Smith1, Azwana R Sadique, Thomas R Cundari

  • 1Department of Chemistry, University of Rochester, Rochester, New York 14267, USA.

Journal of the American Chemical Society
|January 19, 2006
PubMed
まとめ

この研究では,鉄複合体が,二酸化窒素 (N2) の窒素-窒素結合をどのように弱めるかを調査しています. 研究結果は,協同的バック結合とアルカリ金属の減少が,触媒作用に不可欠なN-N結合の弱化を強化することを明らかにしています.

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関連する概念動画

Stereoisomerism02:52

Stereoisomerism

Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...