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Updated: Jul 5, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
06:31

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Published on: November 27, 2015

非対称的環閉オレフィンメタテシスの高度活性キラルルテニウム触媒

Timothy W Funk1, Jacob M Berlin, Robert H Grubbs

  • 1Arnold and Mabel Beckman Laboratory of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA.

Journal of the American Chemical Society
|February 9, 2006
PubMed
まとめ

新しいキラル型N-ヘテロサイクリックカルベンの触媒は,高エナチオセレクティビティの5〜7基の環を合成するために,効率的な非対称環閉メタテシス (ARCM) を可能にします. ヨウ化ナトリウム添加は,多くの基板の性能を大幅に高めます.

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Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether09:21

Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether

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Catalysis02:50

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As shown below, the mechanism involves a nucleophilic attack by water at the carbonyl carbon to form a tetrahedral intermediate. This is followed by the reformation of the carbon–oxygen π bond along with the departure of a halide ion. A final proton transfer step yields carboxylic acid...
Acid Halides to Esters: Alcoholysis01:12

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Catalysis01:27

Catalysis

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