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Updated: Jul 30, 2026

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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mu-eta2:eta2-peroxodicopper ((II) コンプレックスと二次ダイアミンリガンド:チロシナースの機能モデル

Liviu M Mirica1, Deanne Jackson Rudd, Michael A Vance

  • 1Department of Chemistry, Stanford University, California 94305, USA.

Journal of the American Chemical Society
|February 24, 2006
PubMed
まとめ

研究者はチロシナゼ酵素を模倣する銅二酸化酸素複合体を合成した. 銅と酸素のコアを備えたこの複合体は,基板との反応性を示し,生物無機化学アプリケーションの機能モデルとしての可能性を実証しています.

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Polydentate ligands are most widely used in complexometric titrations because they form more stable complexes with the metal ions than mono- or bidentate ligands due to the chelate effect. Examples of polydentate ligands are ethylenediaminetetraacetic acid (EDTA), crown ethers, and cryptands. The most important feature of optimal polydentate ligands is the ability to form 1:1 complexes in a single-step process. Amino carboxylic acid derivatives are frequently used as complexing agents. EDTA is...
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