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Updated: Aug 10, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
09:37

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

3,3'-Bis(trisarylsilyl) で置換されたビナフトホラート稀土金属触媒は,非対称な水素アミナーションのためのものです

Denis V Gribkov1, Kai C Hultzsch, Frank Hampel

  • 1Institut für Organische Chemie, Friedrich-Alexander Universität Erlangen-Nürnberg, Henkestrasse 42, D-91054 Erlangen, Germany.

Journal of the American Chemical Society
|March 16, 2006
PubMed
まとめ

新しいキラルな希土金属複合体は,アミノアルケンの非対称な水素アミナ化/循環反応を効率的に触媒化し,高収量と95%eまでエナチオ選択性を達成します. これらの触媒はまた,優れたダイアステレオ選択性を持つキラルアミノアルケンの運動分解を可能にします.

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